Product ID:ACRYLIC LACQUER SYSTEM, LAC-BL
MSDS Date:04/01/1991
FSC:8010
NIIN:00N046926
MSDS Number: BSWLJ

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: MART2

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK

RTECS: 9999999ZZ

HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ANIMAL

RTECS: 9999999ZZ

EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD KIDNEYS &

RTECS: 9999999ZZ

ACETATE (EGBEA). (EXTRACTED FROM DHHS (NIOSH)

RTECS: 9999999ZZ

ING 3 MAY ALSO REQ TESTING FOR EXTRACTABILITY.

RTECS: 9999999ZZ

DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS

RTECS: 9999999ZZ

TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE &

RTECS: 9999999ZZ

VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT

RTECS: 9999999ZZ

CONSULT OSHA'S STD FOR OCCUP EXPOS TO LEAD

RTECS: 9999999ZZ

FURNITURE/DWELLING/ETC WHICH MAY BE USED BY

RTECS: 9999999ZZ

MSHA APPRVD PARTICULATE RESP FOR PROTECTION

RTECS: 9999999ZZ

22.

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 20-40%

OSHA PEL 200 PPM;150 PPM STEL

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

33.

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 5%

OSHA PEL 400 PPM;500 PPM STEL

ACGIH TLV: 400 PPM;500 PPM STEL

70.

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 10-20%

OSHA PEL 200 PPM;300 PPM STEL

ACGIH TLV: 200 PPM;300 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 5-25%

OSHA PEL 100 PPM;75 PPM STEL

ACGIH TLV: 50 PPM;75 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (SARA III).

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 0-5%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (SARA III).

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 0-5%

OSHA PEL 150 PPM;200 PPM STEL

ACGIH TLV: 150 PPM;200 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHANOL, 2-BUTOXY-, ACETATE; (2-BUTOXYETHYL ACETATE)

CAS: 112-07-2

RTECS: KJ8925000

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 0-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

LEAD CMPD - 9.1% MAX,

CAS: 1344-37-2

Fraction By Weight: <15%

OSHA PEL N/K

ACGIH TLV: N/K

MOLYBDATE ORANGE

CAS: 12656-85-8

RTECS: QA4660000

Fraction By Weight: <15%

OSHA PEL N/K

ACGIH TLV: N/K

5.2-8.1 LBS/GAL.

RTECS: 9999999VO

Fraction By Weight: SEE ING

OSHA PEL N/K

ACGIH TLV: N/K

GRP 1. NTP 6TH ANNUAL RPT ON CARCINS,

RTECS: 9999999ZZ

ADVERSE EFTS TO LIVER, URINARY, BLOOD

RTECS: 9999999ZZ

TO SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ALCOHOLS & ACETATES CAN BE ABSORBED
THRU SKIN. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS
DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH,
DIZZ, NAUS & LOSS OF COORD ARE IN DICATIONS OF EXCESSIVE EXPOS TO
VAPS/SPRAY MIST. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:MOLYBDATE ORANGE:IARC MONOGRAPHS ON EVAL
OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 49, 1990:GRP 1.
CHROMIUM: (SUPDAT)
Effects of Overexposure:HLTH HAZ:EXCESSIVE SKIN EXPOS. CHRONIC:MAY RSLT
IN DMG TO NERV SYS. EMBRYOTOX EFTS. SYMPS INCL ABDOM
DISCOMFORT/PAIN. CONSTIP, LOSS OF APPETITE, METALLIC TASTE, NAUS,
INSOM, NERV IRRITABILITY, WEAK, M USCLE & JOINT PAINS, HDCH & DIZZ.
ING 3MAY INCR NERV SYS EFTS OF OTHER SOLVS. OVEREXP TO SOLV INGS
MAY CAUSE (ING 13)
Medical Cond Aggravated by Exposure:NONE KNOWN

First Aid:INHAL:IF ANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE THE
AREA & GET FRESH AIR. IF PROBLEMS REMAIN OR OCCUR LATER,
IMMEDIATELY GET MEDICAL ATTENTION. SKIN:WASH AFFECTED AREA
THOROUGHLY W/ SOAP & WAT ER. REMOVE CONTAMINATED CLOTHING & LAUNDER
BEFORE RE-USE. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. INGEST:GET MEDICAL ATTENTION.

Flash Point:>21F,>-6C
Lower Limits:0.5%
Upper Limits:3.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. WATER SPRAY MAY
BE INEFFECTIVE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
IF WATER USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILD-UP & (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS(SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DOL STOR CATEGORY - 1B. CONTENTS ARE
FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. KEEP CNTNR CLSD WHEN
NOT IN USE. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA
VENTILATED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS &
HEATERS; TURN OFF STOVES, ELEC TOOLS & ANY OTHER SOURCES OF IGNIT.
CONSULT NFPA CODE. USE APP RVD BONDING & GROUNDING PROCS. (ING 21)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT WEAR PROPERLY FITTED NIOSH/MSHA APPRVD ORG VAP/
PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING,
BURNING/ WELDING DRIED F ILM, WEAR NIOSH/MSHA APPRVD (ING 25)
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPT IF EXPOS TO INGS IS
MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA REGS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORK GOGGLES .
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. EXPLO
HAZ:REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS
MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN ME D
ATTN. MATLS TO AVOID:DANGEROUSLY INCRPRESS IN CLSD CNTNRS. EXPLAN
OF CARCIN:IARC MONOGRAPHS, VOL 49, PG 49, (ING 12)

HCC:F3
Boiling Pt:B.P. Text:>132F,>56C
Vapor Density:HVR/AIR
Spec Gravity:0.9-0.99
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:75-85

Stability Indicator/Materials to Avoid:YES
METALLICS CONTAIN ALUMINUM. CONTAM W/WATER, ACIDS, ALKALIS CAN CAUSE
EVOLUTION OF HYDROGEN, WHICH MAY RSLT IN (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA (40 CFR 251). WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERMINE APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PRODS CNTNG
LEAD/CHROMIUM MUST BE TESTED FOR EXTRACTABLITY. WASTE FROM PRODS
CNTNG(ING 19)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.